Shamans at Purdue University have taken a different tack from the Danish on generating hydrogen for fuel. Rather than taking it with you in a stable container, these guys have figured out a pretty efficient way of generating it as you need it. Their process splits water into hydrogen and oxygen using and alloy of aluminum and gallium. It’s the same thing you did in High School chem class, but there’s no need for an electrical power source because the aluminum reacts to the water by attracting oxygen and releasing hydrogen. The gallium is used to keep the aluminum from ‘rusting’ which will stop the reactive process.
The gallium is a critical component because it hinders the formation of an aluminum oxide skin normally created on aluminum’s surface after bonding with oxygen, a process called oxidation. This skin usually acts as a barrier and prevents oxygen from reacting with aluminum. Reducing the skin’s protective properties allows the reaction to continue until all of the aluminum is used to generate hydrogen, said Jerry Woodall, a distinguished professor of electrical and computer engineering at Purdue who invented the process.
So basically, you fill a tank full of water. The tank has this aluminum gallium alloy in it. The alloy starts to bleed off hydrogen and you’ve got a fuel source. Pretty nifty, I think. What’s even niftier is that the alloy is recyclable.
The gallium component is inert, which means it can be recovered and reused.
“This is especially important because of the currently much higher cost of gallium compared with aluminum,” Woodall said. “Because gallium can be recovered, this makes the process economically viable and more attractive for large-scale use. Also, since the gallium can be of low purity, the cost of impure gallium is ultimately expected to be many times lower than the high-purity gallium used in the electronics industry.”
As the alloy reacts with water, the aluminum turns into aluminum oxide, also called alumina, which can be recycled back into aluminum. The recycled aluminum would be less expensive than mining the metal, making the technology more competitive with other forms of energy production, Woodall said.
I said it before (not on this blog), and I’ll say it again. When my son is my age, the gasoline-powered internal combustion engine will be a thing of the past, a museum piece, and a chapter in an history text book. Now they just need to perfect the flying car and the personal jet pack.
Interesting stuff, but alas, not perfected (yet).
1. You still have to lug around water
2. “The thermodynamic efficiency of the aluminum smelting process is said to be approximately 50 percent. Therefore, at most no more than half the energy that goes into smelting aluminum could be recovered by a fuel cell.”
http://en.wikipedia.org/wiki/Gallium#_note-7
3. Proton Exchange Membrane fuel cells require platinum as the catalyst which is one the most rare expensive elements on earth!
http://en.wikipedia.org/wiki/Platinum
The following wikipedia article sums up the current array of fuel cell technologies pretty well I think.
http://en.wikipedia.org/wiki/Fuel_cell#_note-11
The high efficiency cells show the most promise.
One of those being solid oxide fuel cells which can be fed ammonia directly albeit at relatively high temperatures.
The comment thread on this blog to the original Purdue press release is enlightening as well.
http://www.greencarcongress.com/2007/08/purdue-research.html
Ever since I was a kid people have been telling me about some dude who invented a car that runs on water, but the oil companies either bought and buried the patent or had the dude rubbed out in a joint operation with the CIA and/or Nixon. I never believed the story before, but it appears that these Purdue guys should be thankful that Nixon’s dead.
Their future’s so bright they gotta wear shades…
1) Not sure why lugging around water is bad. At least it doesn’t ignite if we get in an accident. If we had this technology back in the 70′s, the Pinto would still be around. We do lug around gallons of gasoline now.
2) Just the fact that there are all of these different technologies being developed is fantastic.
3) I’m sure Nixon’s head is around here somewhere. (blatant Futurama reference)
1. it was a reference to the title of this post
2. thank god
3. ewww! what’s that smell?!